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Accession number;99A0228207
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| Title;Halide anion recognition using N-confused porphyrin. |
| Author;
FURUTA HIROYUKI
(Kyoto Univ., Grad. Sch.)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.13th;NO.;PAGE.55-57(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The MacDonald-type [3+1] condensation gives rise to amido type meso-free .BETA.-alkyl-substituted N-confused porphyrins (1). A single crystal X-ray diffraction analysis of the corresponding monohydrochloride salt revealed a chloride bridged dimer structure. On the basis of NMR, 1-HCl exists as dimers in dichloromethane solution. The thermodynamic parameters for the Cl- mediated dimer formation in CD2Cl2 were determined. (author abst.) |
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