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Accession number;99A0156463
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| Title;Optically Active Poly- and Oligo(biphenyl carbonate)s as Stable Helical Molecules. |
| Author;
MURAKAWA K
(Osaka Prefecture Univ., Osaka)
FURUSHO Y
(Osaka Prefecture Univ., Osaka)
TAKATA T
(Osaka Prefecture Univ., Osaka)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.93-94(1999)
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| Figure&Table&Reference;FIG.2, REF.16 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Low molecular weight polycarbonate ((R)-2) derived from polycondensation of (R)-4,4',6,6'-tetramethyl-2,2'-dihydroxybiphenyl ((R)-3) showed large Cotton effect at 210 nm compared with its unit model. CD spectra of model oligomers of (R)-2 (2-8mers) obtained by stepwise synthesis and their structure simulation suggested that (R)-2 and higher oligomers can hold a stable left-handed helix. (author abst.) |
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