Synthesis and Structure of Rhodium and Palladium Complexes Bearing Hypervalent Phosphorus Ligand.
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Accession number;99A0308702
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| Title;Synthesis and Structure of Rhodium and Palladium Complexes Bearing Hypervalent Phosphorus Ligand. |
| Author;
TOYOTA K
(Hiroshima Univ., Higashi-hiroshima)
YAMAMOTO Y
(Hiroshima Univ., Higashi-hiroshima)
AKIBA K
(Hiroshima Univ., Higashi-hiroshima)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.18-19(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;The Reaction of lithium phosphoranide Rf2P-Li+(Rf=o-C6H4C(CF3)2O-) with PdCl2(bisphosphine) or[Cp*RhCl2]2 gave novel transition metal complexes bearing transition metal-hypervalent phosphorus bond, Rf2PPdCl(bisphosphine) 1(bisphosphine=dppe), 2(bisphosphine=dmpe), or Rf2PRhCp*Cl 3 in good yields(73-92%). Palladium complexes 1 and 2 reacted with AgSbF6 to give stable cationic complexes[Rf2PPd(L)(bisphosphine)]+SbF6-(4-8: L=MeCN, PhCN, Me3P, PhCHO, 83-96%). The structures of benzaldehyde-palladium cation complex 8 and rhodium complex 4 could be determined by X-ray structural analyses. (author abst.) |
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