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Accession number;99A0308709
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| Title;Synthesis and Selective Reactions of Mixed Halosilanes. |
| Author;
OCHI T
(Hiroshima Univ., Hiroshima)
HIGASHI M
(Hiroshima Univ., Hiroshima)
OHSHITA J
(Hiroshima Univ., Hiroshima)
KUNAI A
(Hiroshima Univ., Hiroshima)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.32-33(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Treatment of n-Hex2SiFCl with 1 equiv of Grignard(RMgBr) and organolithium reagents(RLi) gave n-Hex2SiRF, exclusively. None of n-Hex2SiRCl was obtained. Selective hydrolysis of n-Hex2SiFCl gave n-Hex2SiF-O-Si(n-Hex)2F which was treated with 5,5'-dilithio-2,2'-bithiophene to give a siloxane-bithiophene alternating polymer. (author abst.) |
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