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Accession number;99A0308714
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| Title;Photoinduced Electron-Transfer Bis-silylation of Unsaturated Compounds. |
| Author;
MAEDA Y
(Niigata Univ., Niigata)
WAKAHARA T
(Niigata Univ., Niigata)
AKASAKA T
(Niigata Univ., Niigata)
FUJITSUKA M
(Tohoku Univ., Sendai)
ITO O
(Tohoku Univ., Sendai)
KAKO M
(Univ. Electro-communications, Tokyo)
NAKADAIRA Y
(Univ. Electro-communications, Tokyo)
KOBAYASHI K
(Tokyo Metropolitan Univ., Tokyo)
NAGASE S
(Tokyo Metropolitan Univ., Tokyo)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.42-43(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;We found new photochemical bis-silylation of unsaturated compounds in the presence of C60 via a photoinduced electron-transfer process. Irradiation of a benzonitrile solution of disilirane and C60 with a halogen lamp(cutoff<400nm) resulted in formation of the 1:1 and 1:2 adducts of disilirane and benzonitrile in good yields. This bis-silylation is initiated by an electron-transfer between disilirane and TC60. (author abst.) |
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