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Accession number;99A0308718
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| Title;Reaction of Vinyldisilanes with Ruthenium Carbonyl. |
| Author;
DAI X
(Univ. Electro-communications, Tokyo)
KANO N
(Univ. Electro-communications, Tokyo)
KAKO M
(Univ. Electro-communications, Tokyo)
NAKADAIRA Y
(Univ. Electro-communications, Tokyo)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.50-51(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Reaction of .BETA.-styrylpentamethyldisilane(1a) with Ru3(CO)12 afforded .BETA.-styryltrimethylsilane(2a) with elimination of a dimethylsilylene unit, while under similar conditions .ALPHA.-isomer(1b) was reacted with Ru3(CH)12 together with 1a instead of .ALPHA.-isomer 2b. Under similar conditions their hydrogen analogs, .BETA.- and .ALPHA.-styryldimethytlsilanes(3a and 3b) both gave styrene with elimination of the dimethylsilylene unit. On the other hand, in the presence of methanol 1a gave .BETA.-styryldimethylmethoxysilane(4a), while 1b gave 4b together with its .ALPHA.-isomer 4a. (author abst.) |
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