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Accession number;99A0308724
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| Title;Dehydrogenative Coupling Reactions Between Hydrosilanes and Alkynes Catalyzed by Metal Compounds. |
| Author;
ISHIKAWA J
(Mitsui Chemicals, Inc.)
INOUE K
(Mitsui Chemicals, Inc.)
IWATA K
(Mitsui Chemicals, Inc.)
ITOH M
(Mitsui Chemicals, Inc.)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.62-63(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Dehydrogenative coupling reaction between phenylsilane and ethynylbenzene occurred in the presence of metal alkoxide, alkylmetals, or metal amide. Barium alkoxide showed the highest activity and selectivity for the reaction, and gave the polymer in the reaction of phenylsilane with m-diethynylbenzene. A reaction mechanism involving metal acetylide was proposed. (author abst.) |
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