Friedel-Crafts Reactions of Organometallic Compounds with Graphite as a Catalyst.

Accession number;99A0308729
Title;Friedel-Crafts Reactions of Organometallic Compounds with Graphite as a Catalyst.
Author; SEKI K (Sophia Univ., Tokyo) SHIMURA J (Sophia Univ., Tokyo) TAKAYAMA C (Sophia Univ., Tokyo) HATTORI K (Sophia Univ., Tokyo) SUGIYAMA T (Sophia Univ., Tokyo) KAJITANI M (Sophia Univ., Tokyo) SUGIMORI A (Sophia Univ., Tokyo) KODOMARI M (Shibaura Inst. Technol., Tokyo)
Journal Title;Abstr Symp Organomet Chem Jpn
Journal Code:L0853A
ISSN:
VOL.45th;NO.;PAGE.72-73(1998)
Figure&Table&Reference;
Pub. Country;Japan
Language;English
Abstract;Graphite powder catalyzes Friedel-Crafts type acylation in pseudo-aromatic rings in organometallic compounds(Cp rings coordinated to metal, conjugated metal chelate rings such as metalladithiolene complexes, acetylacetonatometal complexes etc.). The method is proved to be a useful method to introduce an acyl group into the pseudo-aromaic rings in organometallic compounds as well as those in typical electron-rich organic compounds such as anisole. (author abst.)