Complexation Behavior of Chiral 1,1'-Bis(oxazolinyl)ferrocene Ligands with C2-Symmetry.
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Accession number;99A0308730
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| Title;Complexation Behavior of Chiral 1,1'-Bis(oxazolinyl)ferrocene Ligands with C2-Symmetry. |
| Author;
IMAI Y
(Osaka Univ., Osaka, Jpn)
ZHANG W
(Osaka Univ., Osaka, Jpn)
KIDA T
(Osaka Univ., Osaka, Jpn)
NAKATSUJI Y
(Osaka Univ., Osaka, Jpn)
IKEDA I
(Osaka Univ., Osaka, Jpn)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.74-75(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Upon complexation with Pd(II), both chiral 1,1'-bis(oxazolinyl)ferrocene ligand 2 and its planar chiral derivative 3 afforded a 1:2 ligand-Pd(II) complex. On the other hand, upon complexation with copper(I) chloride, both 2 and 3 afforded only one of the two possible diastereomeric 1:1 ligand-Cu(I) complexes. The copper(I) complexes of 2 and 3 have the opposite twists of the two Cp rings each other, which is ascribed to the effect of the planar chirality in 3. (author abst.) |
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