Synthesis and Reactivity of Highly Electron Deficient Alkyl Complexes Supported by Tp Ligand.
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Accession number;99A0308734
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| Title;Synthesis and Reactivity of Highly Electron Deficient Alkyl Complexes Supported by Tp Ligand. |
| Author;
SHIRASAWA N
(Tokyo Inst. Technol., Yokohama, Jpn)
HIKICHI S
(Tokyo Inst. Technol., Yokohama, Jpn)
AKITA M
(Tokyo Inst. Technol., Yokohama, Jpn)
MORO-OKA Y
(Tokyo Inst. Technol., Yokohama, Jpn)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.82-83(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;TpiPrM-R, .ETA.1-benzyl-type(R=p-tolylmethyl, .ALPHA.-naphthylmethyl) and .ETA.1-ethyl complexes of Fe and Co supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), are synthesized and characterized by X-ray crystallography. These complexes are electron deficient species with 14 and 15 valence electrons and it is notable that no .BETA.-elimination is observed for the ethyl complexes. (author abst.) |
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