Formation and Reactions of Diarylgermanones, Novel Germanium-Containing Doubly Bonded Species.
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Accession number;99A0308740
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| Title;Formation and Reactions of Diarylgermanones, Novel Germanium-Containing Doubly Bonded Species. |
| Author;
TOKITOH N
(Kyushu Univ., Fukuoka)
MATSUMOTO T
(Univ. Tokyo, Tokyo)
KISHIKAWA K
(Univ. Tokyo, Tokyo)
OKAZAKI R
(Japan Women's Univ., Tokyo)
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Journal Title;Abstr Symp Organomet Chem Jpn
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Journal Code:L0853A
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ISSN:
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VOL.45th;NO.;PAGE.94-95(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Overcrowded diarylgermanones, a novel class of double-bond species between germanium and oxygen, were successfully generated by the following three different methods; i) the reaction of a kinetically stabilized diarylgermylene with an amine N-oxide, ii) oxygenation of a germylene with molecular oxygen, and iii) thermal retrocycloaddition of a sterically crowded oxazagermete derivative. Thermal stability and inter- and intramolecular reactivities of the germanones thus generated were also examined. (author abst.) |
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