Synthesis and Structure of a Stable Cyclic Dialkylgermylene.

Accession number;99A0308741
Title;Synthesis and Structure of a Stable Cyclic Dialkylgermylene.
Author; ISHIDA S (Tohoku Univ., Sendai) IWAMOTO T (Tohoku Univ., Sendai) KIRA M (Tohoku Univ., Sendai)
Journal Title;Abstr Symp Organomet Chem Jpn
Journal Code:L0853A
ISSN:
VOL.45th;NO.;PAGE.96-97(1998)
Figure&Table&Reference;
Pub. Country;Japan
Language;English
Abstract;A stable cyclic dialkylgermylene (1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 was observed by variable-temperature UV-vis spectroscopy and X-ray crystallography to have a monomeric structure both in solution and in the solid state. (author abst.)