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Accession number;99A0156452
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| Title;Chiral Lewis Acid Catalysis in Aqueous Media. Catalytic Asymmetric Aldol Reactions of Silyl Enol Ethers with Aldehydes in a Protic Solvent Including Water. |
| Author;
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.71-72(1999)
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| Figure&Table&Reference;TBL.1, REF.37 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Chiral copper(II)-catalyzed asymmetric aldol reactions of silyl enol ethers with aldehydes have been successfully carried out in a water-ethanol solution. The use of the protic solvent including water is essential in these reactions, and this report has proposed and demonstrated a new concept for solvents in catalytic asymmetric aldol reactions. (author abst.) |
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