Diastereoselective Specificity for the Hydrolysis of Dipeptide Esters in Aqueous Media.
|
Accession number;99A0156453
|
| Title;Diastereoselective Specificity for the Hydrolysis of Dipeptide Esters in Aqueous Media. |
| Author;
UEOKA R
(Kumamoto Inst. Technol., kumamoto)
GOTO K
(Kumamoto Inst. Technol., kumamoto)
TANOUE O
(Kumamoto Inst. Technol., kumamoto)
MIKI A
(Kumamoto Inst. Technol., kumamoto)
YOSHIMITSU S
(Kumamoto Inst. Technol., kumamoto)
MURAKAMI Y
(Kumamoto Inst. Technol., kumamoto)
IMAMURA C
(Yamaguchi Prefectural Univ., Yamaguchi)
IHARA Y
(Yamaguchi Prefectural Univ., Yamaguchi)
|
Journal Title;Chem Lett
|
Journal Code:S0742A
|
ISSN:0366-7022
|
|
VOL.;NO.1;PAGE.73-74(1999)
|
| Figure&Table&Reference;FIG.3, REF.11 |
| Pub. Country;Japan |
| Language;English |
| Abstract;The diastereoselectivity for the hydrolysis of p-methoxycarbonylphenyl N-(benzyloxycarbonyl)-D(L)-phenylalanyl-L-leucinate in aqueous solution was inverted by changing concentrations of the substrates or the reaction temperature. The monomer-aggregate transition operated on the LL-substrate, which was suggested by the spectroscopic measurements, seems to be responsible for such behavior. (author abst.) |
|
|
|
Related Articles;
|
|
|
