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Accession number;99A0156454
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| Title;A Novel Rearrangement of Chromium Allyloxy(aryl)carbene Complexes Catalyzed by Pd(0). |
| Author;
SAKURAI H
(Univ. Tokyo, Tokyo)
TANABE K
(Univ. Tokyo, Tokyo)
NARASAKA K
(Univ. Tokyo, Tokyo)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.75-76(1999)
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| Figure&Table&Reference;TBL.3, REF.22 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Chromium allyloxy(aryl)carbene complexes undergo formal [2,3]- or [1,2]-sigmatropic rearrangement by the catalytic use of Pd(PPh3)4 under CO atmosphere. The reaction is considered to proceed via palladium aroyl .PI.-allyl complex, which is converted to the corresponding aryl ketones by reductive elimination. (author abst.) |
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