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Accession number;99A0156457
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| Title;Catalytic Hydrocarbon Oxygenation by a Dinuclear Ruthenium(II) Complex with Molecular Oxygen. |
| Author;
KOJIMA T
(Kyushu Univ., Fukuoka)
MATSUDA Y
(Kyushu Univ., Fukuoka)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.81-82(1999)
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| Figure&Table&Reference;TBL.1, REF.16 |
| Pub. Country;Japan |
| Language;English |
| Abstract;A his-.MU.-chloro Ru(II) dimer with tris(2-pyridylmethyl)amine (TPA) exhibited catalytic oxygenation of alkenes and cooxygenation of alkanes in the presence of cyclohexene with molecular oxygen (1atm) at room temperature without reducing reagents; reactions proceeded via a radical chain mechanism as a main pathway. (author abst.) |
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