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Accession number;99A0156458
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| Title;Methanol Formation from Dichloromethane under Hydrothermal Conditions. |
| Author;
YAMASAKI Y
(Tohoku Univ., Sendai)
ENOMOTO H
(Tohoku Univ., Sendai)
YAMASAKI N
(Kochi Univ., Kochi)
NAKAHARA M
(Kyoto Univ., Kyoto)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.83-84(1999)
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| Figure&Table&Reference;FIG.2, REF.9 |
| Pub. Country;Japan |
| Language;English |
| Abstract;CH2Cl2 (1 mole) mixed with NaOH (2 moles) was treated under hydrothermal conditions at 250.DEG.C.. The chlorinated methane was completely hydrolyzed to form methanol and the formate by the Cannizzaro reaction. The reactant and products were analyzed by 1H-, 2H-, and 13C-NMR. Solvent isotope effect on the transformation was also investigated. The hazardous and environmentally troublesome organic solvent was safely converted into the useful compounds. (author abst.) |
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