Elongated H-H in trans-[Os(.ETA.2-H2)en2Cl]Cl.
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Accession number;99A0156420
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| Title;Elongated H-H in trans-[Os(.ETA.2-H2)en2Cl]Cl. |
| Author;
HASEGAWA T
(Stanford Univ., Ca, Usa)
LI Z
(Stanford Univ., Ca, Usa)
TAUBE H
(Stanford Univ., Ca, Usa)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.7-8(1999)
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| Figure&Table&Reference;FIG.3, REF.18 |
| Pub. Country;Japan |
| Language;English |
| Abstract;The structure of trans-[Os(.ETA.2-H2)en2Cl]Cl has been determined by X-ray analysis of a crystal at 118(2) K. A study of the two independent crystals confirms the trans arrangement. In both crystals the H-H bonds orientate along the N-Os axis and the H-H distances are in the mid-range between those of dihydride compounds and of dihydrogen. (author abst.) |
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