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Accession number;99A0711815
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| Title;Asymmetric Friedel-Crafts reaction with fluoral by BINOL-Ti catalysts. |
| Author;
MIKAMI KOICHI
(Tokyo Inst. of Technol. Fac. of Eng.)
ISHII AKIHIRO
(Tokyo Inst. of Technol. Fac. of Eng.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.22nd;NO.;PAGE.6-7(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The Friedel-Crafts reaction is one of the most fundamental C-C bond forming reactions in organic synthesis. However, its application to asymmetric synthesis of organofluorine compounds has been quite limited. We report the asymmetric Friedel-Crafts reaction with fluoral catalyzed be chiral BINOL-Ti complexes. Furthermore, when a silyl enol ether is employed as a substrate, the Friedel-Crafts-type Mukoyama aldol product, namely the silyl enol ether was obtained. (author abst.) |
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