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Accession number;99A0711818
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| Title;Contorol of photosensitisation activity of p-terphenyl by partially fluorination. |
| Author;
KITAMURA TAKAYUKI
(Osaka Univ., Grad. Sch.)
WADA YUJI
(Osaka Univ., Grad. Sch.)
MURAKOSHI KEI
(Osaka Univ., Grad. Sch.)
YANAGIDA SHOZO
(Osaka Univ., Grad. Sch.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.22nd;NO.;PAGE.14-15(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;We attempt to control of photosensitization activities of p-terphenyl which works as a photosensitizer for catalytic electron transfer under UV-light irradiation by partially fluorination. Increasing the number of fluorine substitution, absorption spectrum shifted to shorter wavelength and oxidation potential shifted to positive. The activity of p-terphenyls was examined in photooxidation of water to hydroxyl radicals. It was revealed that fluorination enhanced the activity and perfluorinated one had extreme activity. (author abst.) |
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