|
Accession number;99A0711826
|
| Title;Direct generation of .ALPHA.-fluoromalonaldehyde by the use of fluorinated enol sulfonate and its synthetic utilization. |
| Author;
FUNABIKI KAZUMASA
(Gifu Univ., Fac. of Eng.)
FUKUSHIMA YOSHITAKA
(Gifu Univ., Fac. of Eng.)
MATSUI MASAKI
(Gifu Univ., Fac. of Eng.)
SHIBATA KATSUYOSHI
(Gifu Univ., Fac. of Eng.)
|
Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
|
Journal Code:F0135B
|
ISSN:
|
|
VOL.22nd;NO.;PAGE.30-31(1998)
|
| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Treatment of 2,3,3-trifluoro-1-propenyl p-toluenesulfonate in the presence of sodium hydroxide in a mixed solvent of dimethyl sulfoxide (DMSO)-water (H2O) (1:1) at room temperature result in successful generation of .ALPHA.-fluoromalonaldehyde sodium salt, which readily reacts with acid chlorides to give the corresponding (Z)-.BETA.-acyloxy-.ALPHA.-fluoroacrylaldehydes in good to excellent yields. (author abst.) |
|
|
|
Related Articles;
|
