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Accession number;99A0711829
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| Title;Radical carbon-carbon bond formation reaction of chloro- or bromodifluoromethyl carbinols. |
| Author;
ITO TAKATOSHI
(Mie Univ., Fac. of Eng.)
SHIMIZU MAKOTO
(Mie Univ., Fac. of Eng.)
FUJISAWA TAMOTSU
(Mie Univ., Fac. of Eng.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.22nd;NO.;PAGE.36-37(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Acylation of aromatic compounds with fluorine contained .BETA.-propiolactone smoothly proceeds to give the corresponding acylated chlorodifluoromethyl carbinol. Radical cyclization of allyl ethers derived from chiral chlorodifluoromethyl carbinols gives oxygen contained 5-membered heterocycles in good yields. Further intermolecular radical reaction of bromodifluoromethyl carbinol with allyltributyltin gave the corresponding of allyl substituted compounds in reasonable yields. (author abst.) |
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