Synthesis and propeties of fluoroalkylated end-capped acrylamide oligomers.

Accession number;99A0711834
Title;Synthesis and propeties of fluoroalkylated end-capped acrylamide oligomers.
Author; SAWADA HIDEO (Nara Natl. Coll. of Technol.) YOSHINO YOSHIKO (Nara Natl. Coll. of Technol.) KAWASE TOKUZO (Osaka City Univ.)
Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
Journal Code:F0135B
ISSN:
VOL.22nd;NO.;PAGE.46-47(1998)
Figure&Table&Reference;
Pub. Country;Japan
Language;Japanese
Abstract;Fluoroalkylated end-capped acrylamide oligomers were prepared by the reaction of fluoroalkanoyl peroxides with N-(1,1-dimethyl-3-oxobutyl)acrylamide,N-(2-hydroxylpropyl)methacrylamide, or N,N-(2,2-dihydroxyethyl)acrylamide. These fluorinated oligomers thus obtained were able to reduce the surface tension of xylene or water, effectively. Therefore, these oligomers are useful for novel fluorinated oligomeric surfactants. Furthermore, it was demonstrated that these oligomers form the molecular aggregates, and metal ions act as guest molecules for these aggregates. (author abst.)