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Accession number;99A0711839
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| Title;Reaction of a hexafluoropropene-diethylamine adduct (PPDA) with propargyl alcohols and its utilization for organic synthesis. |
| Author;
OGU KEN'ICHI
(Chiba Univ., Fac. of Eng.)
OGURA KATSUYUKI
(Chiba Univ., Fac. of Eng.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.22nd;NO.;PAGE.56-57(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The reaction of a hexafluoropropene-diethyl amine adduct (PPDA) with propargyl alcohols in the presence of N,N-diisopropylethlamines afforded 2-fluoro-2-trifluoromethyl-3,4-alkadienamides in good yields. When 2-butyn-1,4-diol was applied to the reaction, 1,3-diene was afforded as a major product along with 3-hydroxymethyl-3,4-pentadienamide. (author abst.) |
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