Reaction of MeOF with perfluoroolefins.

Accession number;99A0711842
Title;Reaction of MeOF with perfluoroolefins.
Author; SUZUTA TETSUYA (Rite) ABE TAKASHI (Gov. Ind. Res. Inst., Nagoya, Agency of Ind. Sci and Technol.) SEKIYA AKIRA (National Inst. Materials and Chemical Res.)
Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
Journal Code:F0135B
ISSN:
VOL.22nd;NO.;PAGE.64-65(1998)
Figure&Table&Reference;
Pub. Country;Japan
Language;Japanese
Abstract;We examined reaction of MeOF with perfluoroolefines and obtained addition products in good yields for first time. From the result of reaction of MeOF with hexafluoropropene, MeO was added to the end group of CF2 to form CF3CF2CF2OMe. The result is supported by the ab initio calculation of MeO+ with the olefin. (author abst.)