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Accession number;99A0711855
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| Title;Computational investigation on structures and acidities of various fluorine-containing strong acid. |
| Author;
KAMIZORI HARUKI
(Kyushu Univ.)
SONODA TAKAAKI
(Kyushu Univ.)
NAGASHIMA HIDEO
(Kyushu Univ., Inst. of Adv. Mater. Study)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.22nd;NO.;PAGE.92-93(1998)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;In our study on the development of new type of lithium battery electrolytes, MO calculations were carried out to determine the rerative stabilizing energy .DELTA..DELTA.E and HOMO energy E(HOMO) of various kinds of fluorine-containing anions with oxygen, nitorogen and carbon as their anion center. The investigation of relationship between gas-phase acidity (.DELTA.Gacid) of strong fluorine-containing Br.PHI.nsted acids and .DELTA..DELTA.E and that between .DELTA.Gacid and E(HOMO) gave good linear correlations. (author abst.) |
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