Chemical Behaviour of Rutherfordium (Rf, Element 104) in Ion-Exchanger.
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Accession number;99A1007970
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| Title;Chemical Behaviour of Rutherfordium (Rf, Element 104) in Ion-Exchanger. |
| Author;
TSUKADAKA ZUAKI
(Japan Atomic Energy Res. Inst., Advanced Sci. Res. Center, JPN)
BRUECHLE W
(Gesellschaft Fuer Schwerionenforsch. (gsi))
EICHLER R
(Paul Scherrer Insti. (psi))
GAERTNER M
(Univ. Bern)
GLATZ J P
(Itu)
KIRBACH U
(Technol. Univ. Dresden)
KRATZ J V
(Univ. Mainz)
NAGAME YUICHIRO
(Japan Atomic Energy Res. Inst., Advanced Sci. Res. Center, JPN)
ZAUNER S
(Univ. Mainz)
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Journal Title;Abstracts of Papers. Symposium on Radiochemistry
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Journal Code:F0139B
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ISSN:1345-2762
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VOL.43rd;NO.;PAGE.55(1999)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The Kd values of Rf at various HF concentrations under condition of 0.1 M HNO 4+ solution in anion and cation exchange column were compared with the behaviour of other group 4 elements, Zr and Hf, and the pseudo-homologue Th. The data shows Rf behaves differently from group 4 elements and seems to resemble Th on both systems. A first attempt of interpretation could be that the ionic radii of Zr4+ and Hf4+ are very similar due to the lanthanide contraction resulting in similar complexation behaviour, while in Rf, the actinide contraction is surpassed by the relativistic expansion of the d orbitals. (author abst.) |
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