Spin-crossover iron(III) complex containing photoisomeri zation ligand.

Accession number;99A1007986
Title;Spin-crossover iron(III) complex containing photoisomeri zation ligand.
Author; EINAGA YASUAKI (Univ. of Tokyo, Fac. of Eng.) HAYAMI SHIN'YA (Kanagawa Acad. Sci. and Technol. Foundation (KAST)) KOBAYASHI YOSHIO (Riken Inst. of Phys. and Chem. Res.) MAEDA YONEZO (Kyushu Univ., Faculty of Science) FUJISHIMA AKIRA (Univ. of Tokyo, Fac. of Eng.) SATO OSAMU (Kanagawa Acad. Sci. and Technol. Foundation (KAST))
Journal Title;Abstracts of Papers. Symposium on Radiochemistry
Journal Code:F0139B
ISSN:1345-2762
VOL.43rd;NO.;PAGE.71(1999)
Figure&Table&Reference;
Pub. Country;Japan
Language;Japanese
Abstract;Binuclear iron(III) spin-crossover complex [Fe2(salten)2(azo)](BPh4)2 was synthesized and characterized by Moessbauer spectroscopy. This complex contains the ligand which is able to photoisomerize as a bridgingligand. The complex exhibited the spin-crossover behavior. Even in the solid state, high spin state was observed by photo-illumination at room temperature. (author abst.)