Anion Template Syntheses of Porphyrins.

Accession number;00A0163502
Title;Anion Template Syntheses of Porphyrins.
Author; FURUTA HIROYUKI (Kyoto Univ., Grad. Sch.)
Journal Title;Abstracts. Symposium on Biofunctional Chemistry
Journal Code:L0836A
ISSN:
VOL.14th;NO.;PAGE.88-89(1999)
Figure&Table&Reference;
Pub. Country;Japan
Language;Japanese
Abstract;Anion template effects on the porphyrin syntheses were investigated. Tetratolylporphyrin and N-Confused Tetraphenylporphyrin syntheses was undertaken under a various tetrabutylammonium salt. Among the anions, Br-, I- and BF4- were found most effective. The kinetic and thermodynamic template effects by added anion through hydrogen bondings were discussed. (author abst.)