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Accession number;00A0163507
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| Title;Supramolecular Chemistry in Aqueous Solution: Nanometer-Scale Self-Assembly of Tris(Zn2+-cyclen) and Cyanuric Acid. |
| Author;
AOKI SHIN
(Hiroshima Univ., Sch. of Med.)
SHIRO MOTOO
(Rigaku Corp.)
KIMURA EIICHI
(Hiroshima Univ., Sch. of Med.)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.14th;NO.;PAGE.98-99(1999)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Two new supermolecules comprising tris(Zn2+-cyclen)(Zn3L) and cyanuric acid(CA) in aqueous solution are reported. The 1H NMR, UV, ITC experiments have indicated that Zn3L and CA forms 2:3 complex, in which three molecules of CA dianion are sandwiched between two molecules of Zn3L. The second supermolecule, 4:4 complex of Zn3L and CA trianion, was isolated and found to have a cage-like structure of nanometer-scale. (author abst.) |
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