Study on the reliability of analytical methods for the determination of uranium and thorium in semiconductor memory materials.

Accession number;01A0231219
Title;Study on the reliability of analytical methods for the determination of uranium and thorium in semiconductor memory materials.
Author; MITSUGASHIRA TOSHIAKI (Inst. for Mater. Res., Tohoku Univ.) HARA MITSUO (Inst. for Mater. Res., Tohoku Univ.) KIM P (Vacum Met. Co., Ltd.) NAKASHIMA KOICHI (Umatkyushu) NAKAYAMA KOJI (Umatkyushu) KUROIWA YOICHI (Umatkyushu)
Journal Title;Abstracts of Papers. Symposium on Radiochemistry
Journal Code:F0139B
ISSN:1345-2762
VOL.44th;NO.;PAGE.62(2000)
Figure&Table&Reference;
Pub. Country;Japan
Language;Japanese
Abstract;Elimination and the ultra trace analysis of uranium and thorium in memory device materials are important research targets in modern semiconductor industry. Commonly used analytical methods such as RNAA, ICP-MS, GD-MS is valid for long life alpha-emitters and the probability of soft errors is evaluated by assuming the radioequilibrium in natural alpha-decay series without the direct determination of daughter alpha-emitters. Authors compared the analytical results of high-purity aluminum obtained by RNAA, ICP-MS, GD-MS, and Sm-method that is recently developed for the direct determination of decay series alpha-emitters and confirmed that all analytical methods are reliable for the determination of U-238 and Th-232. But radio-disequilibrium enrichment of daughter nuclides is detected by Sm-method. The results imply that the soft-error probability must be evaluated by the analysis of all decay series alpha-emitters. (author abst.)