A Disilanyl Dianion and a Silyl Dianion from a Stable Silylene.
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Accession number;01A0173101
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| Title;A Disilanyl Dianion and a Silyl Dianion from a Stable Silylene. |
| Author;
WEST R
(Univ. Wisconsin-madison, Wi)
SCHMEDAKE T A
(Univ. Wisconsin-madison, Wi)
HAAF M
(Univ. Wisconsin-madison, Wi)
BECKER J
(Ben-gurion Univ. Negev, Beersheva, Isr)
MUELLER T
(Univ. Frankfurt, Frankfurt/main, Deu)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.68-69(2001)
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| Figure&Table&Reference;FIG.1, REF.14 |
| Pub. Country;Japan |
| Language;English |
| Abstract;The stable silylene, N,N'-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane. (author abst.) |
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