Generation and Behavior of 9-Anthroyloxyl Radicals in Photocleavage of N-(9-Anthroyloxy)-9-fluorenylideneamine.
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Accession number;01A0173108
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| Title;Generation and Behavior of 9-Anthroyloxyl Radicals in Photocleavage of N-(9-Anthroyloxy)-9-fluorenylideneamine. |
| Author;
SAITOH Y
(Univ. Tsukuba, Ibaraki)
KANEKO M
(Univ. Tsukuba, Ibaraki)
SEGAWA K
(Univ. Tsukuba, Ibaraki)
ITOH H
(Yamagata Univ., Yamagata)
SAKURAGI H
(Univ. Tsukuba, Ibaraki)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.82-83(2001)
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| Figure&Table&Reference;FIG.2, TBL.1, REF.15 |
| Pub. Country;Japan |
| Language;English |
| Abstract;9-Anthroyloxyl radicals are generated from photocleavage of the N-O bond of N-(9-anthroyloxy)-9-fluorenylideneamine and 1-(9-anthroyloxy)-2-pyridone in acetonitrile. They are much less reactive in decarboxylation, addition to olefins, and hydrogen-atom abstraction than benzoyloxyl and 1-naphthoyloxyl radicals, and supposedly undergo intramolecular addition to the ipso position to give (x-lactonic spiroanthracenyl radicals. (author abst.) |
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