Di-tert-butylphosphate Complexes of Mn(II) and Cu(II) as Single-Source Precursors for Metal Phosphate Materials.
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Accession number;01A0173109
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| Title;Di-tert-butylphosphate Complexes of Mn(II) and Cu(II) as Single-Source Precursors for Metal Phosphate Materials. |
| Author;
MURUGAVEL R
(Indian Inst. Technol.-bombay, Mumbai, Ind)
SATHIYENDIRAN M
(Indian Inst. Technol.-bombay, Mumbai, Ind)
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Journal Title;Chem Lett
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Journal Code:S0742A
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ISSN:0366-7022
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VOL.;NO.1;PAGE.84-85(2001)
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| Figure&Table&Reference;FIG.2, TBL.1, REF.13 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)4] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene, imidazole and water to finally yield the respective ceramic materials Mn(PO3)2 or Cu(PO3)2. (author abst.) |
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