Dichalcogenane Derivatives of Methylenedithio(ethylenedithio)tetrathiafulvalene (MET) and a Derived Metallic Cation-Radical Salt with Screwed Donor Stacks.

Accession number;01A0173110
Title;Dichalcogenane Derivatives of Methylenedithio(ethylenedithio)tetrathiafulvalene (MET) and a Derived Metallic Cation-Radical Salt with Screwed Donor Stacks.
Author; YAMADA J (Himeji Inst. Technol., Hyogo) MANGETSU T (Himeji Inst. Technol., Hyogo) AKUTSU H (Himeji Inst. Technol., Hyogo) NAKATSUJI S (Himeji Inst. Technol., Hyogo) NISHIKAWA H (Tokyo Metropolitan Univ., Tokyo) IKEMOTO I (Tokyo Metropolitan Univ., Tokyo) KIKUCHI K (Tokyo Metropolitan Univ., Tokyo)
Journal Title;Chem Lett
Journal Code:S0742A
ISSN:0366-7022
VOL.;NO.1;PAGE.86-87(2001)
Figure&Table&Reference;FIG.5, TBL.1, REF.9
Pub. Country;Japan
Language;English
Abstract;The synthesis of the dichalcogenane derivatives of MET, (1,3-dioxan-2-yl)methylenedithio(ethylenedithio)tetrathiafulvalene (DOA-MET) and (1,3-dithian-2-yl)methylenedithio(ethylenedithio)tetrathiafulvalene (DTA-MET), and the preparation of their charge-transfer (CT) materials are investigated to explore new organic metals. The resulting (DOA-MET)3Aul2 salt exhibits weak metallic conducting behavior, and has screwed donor stacks. (author abst.)
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