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Accession number;01A0228964
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| Title;Self-Assembly of a Functional Molecular Capsule. |
| Author;
UMEMOTO KAZUHIKO
(Graduate Univ. Advances Studies)
TSUKUI HITOSHI
(Nagoya Univ., Grad. Sch.)
FUJITA MAKOTO
(Nagoya Univ., Grad. Sch.)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.15th;NO.;PAGE.44-45(2000)
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| Figure&Table&Reference;FIG.4, REF.1 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Molecular capsules create isolated microspaces inside their frameworks. Here we report the transition metal-directed assembly of a stable, nanometer sized hexahedral coordination capsule (3) from six triangular exo-pentadentate organic ligands (1) and fifteen transition metals (2). On the other hand, the quantitative assembly of coordination tetrahedral capsule (6) from ligands 5 and transition metals 2 was achieved with the aid of the remarkable template molecule. (author abst.) |
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