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Accession number;01A0228983
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| Title;Unique Stabilization of Mono 1-Methylimidazole Adduct in Ferric Corrphycene Chloride. |
| Author;
NEYA SABURO
(Kyoto Pharm. Univ.)
OGO YOSHIKI
(Toho Univ., Sch. of Med.)
NAKAMURA MIKIO
(Toho Univ., Sch. of Med.)
FUNASAKI NORIAKI
(Kyoto Pharm. Univ.)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.15th;NO.;PAGE.84-85(2000)
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| Figure&Table&Reference;FIG.2 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;We report here unique formation of the mono 1-methylimidazole adduct during equilibrium binding to ferric corrphycene. This is in remarkable contrast to ferric porphyrin where the mono adduct is hardly accumulates. The structural account for the characteristic behavior found in ferric corrphycene was provided on the basis of reactivity changes of ferric iron incorporated into the contracted and trapezoidal coordination core. (author abst.) |
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