Science Links Japan | Electrochemical Influence of Tridentate Polypyrazolylborate Ligands: Syntheses and Electrochemistry of Bis(.ETA.3-polypyrazolylborato)ruthenium(II) Complexes.

Electrochemical Influence of Tridentate Polypyrazolylborate Ligands: Syntheses and Electrochemistry of Bis(.ETA.3-polypyrazolylborato)ruthenium(II) Complexes.

Accession number;01A0302789

Title;Electrochemical Influence of Tridentate Polypyrazolylborate Ligands: Syntheses and Electrochemistry of Bis(.ETA.3-polypyrazolylborato)ruthenium(II) Complexes.

Author; ONISHI M (Nagasaki Univ., Nagasaki) KUMAGAE S (Nagasaki Univ., Nagasaki) ASAI K (Nagasaki Univ., Nagasaki) KAWANO H (Nagasaki Univ., Nagasaki) SHIGEMITSU Y (Industrial Technol. Center Of Nagasaki, Nagasaki)

Journal Title;Chem Lett

Journal Code:S0742A

ISSN:0366-7022

VOL.;NO.2;PAGE.96-97(2001)

Figure&Table&Reference;FIG.1, REF.14

Pub. Country;Japan

Language;English

Abstract;Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(.ETA.3-polypyrazolylborato)ruthenium(II) complexes [Ru(L1)(L2)], two polypyrazolylborate ligands, L1 and L2, were independently exerted on the oxidation half-wave potentials (E1/2) or the couples. Relative contributions .DELTA.E(L) of the respective polypyrazolylborates to the E1/2 values were evaluated. (author abst.)

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