Pressure-Induced Phase Transition of Iodanil.

Accession number;02A0335432
Title;Pressure-Induced Phase Transition of Iodanil.
Author; NAKAYAMA ATSUKO (Sangyogijutsusogoken Shintansokeizairyokaihatsukense) FUJIHISA HIROSHI (Sangyogijutsusogoken) TAKEMURA KEN'ICHI (Butsushitsu・zairyokenkyukiko) AOKI KATSUTOSHI (Sangyogijutsusogoken)
Journal Title;Program and Abstracts of Papers. High Pressure Conference of Japan
Journal Code:L1222A
ISSN:0917-6373
VOL.42nd;NO.;PAGE.12(2001)
Figure&Table&Reference;FIG.1, REF.9
Pub. Country;Japan
Language;Japanese
Abstract;Powder x-ray diffraction measurements of idoanil (C6O2I4) have been carried out at the pressure up to 39 GPa at room temperature with a diamond anvil cell under the best hydrostatic condition using helium pressure-transmitting medium. Iodanil causes no phase transition up to 23.3 GPa and each diffraction pattern up to 23.3 GPa were fitted with a space group P21/c. New peaks indicating the phase transition apperared above 26.8 GPa. The intensities increased with increasing pressure while the originals observed in the low-pressure phase were gradually depressed. This phase transition was accompanied with the mixed state of the low- and high-pressure phases in the wide pressure range between 26.8 and at least 39 GPa. (author abst.)