The Nature of Bonding of Hyperlithiated Molecules Beyond the Octet Rule.
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Accession number;02A0151787
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| Title;The Nature of Bonding of Hyperlithiated Molecules Beyond the Octet Rule. |
| Author;
KUDO H
(Graduate School Of Sci., Tohoku Univ., Japan)
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Journal Title;Abstracts of Papers. Symposium on Radiochemistry
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Journal Code:F0139B
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ISSN:1345-2762
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VOL.45th;NO.;PAGE.5(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Structures and stabilities of hyperlithiated molecules (HLMs) such as LinA (A = C, O, S, P), M2CN (M = Li, Na, K), Li2F and Li2OH as well as Li-rich clusters LinFn-1 (n=3-5) and Lin(OH)n-1(n=3-6) are discussed based on results of both experiments and theoretical calculations. The excess valence electrons delocalized over Li atoms contribute to the formation of a Lin+ cage, enhancing the stability of HLM. (author abst.) |
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