Gas hydrates under high pressure.

Accession number;02A0335445
Title;Gas hydrates under high pressure.
Author; SHIMIZU HIROYASU (Gifudai Daigakuinkankyoenerugishisutemu)
Journal Title;Program and Abstracts of Papers. High Pressure Conference of Japan
Journal Code:L1222A
ISSN:0917-6373
VOL.42nd;NO.;PAGE.25-26(2001)
Figure&Table&Reference;FIG.5, TBL.1
Pub. Country;Japan
Language;Japanese
Abstract;The fundamental properties of gas hydrates are reviewed; classification and type, structure and composition, formation and stability, and occupancy of guest molecules. Recent Raman studies on the properties of cage-occupancy are discussed by considering C-H vibrations of their guest molecules for methane, methane-ethane mixed (structural phase transition), ethane, and cyclopropane (pressure-induced small cage occupancy) hydrates. Finally, I give an overview of very recent x-ray (neutron) and Raman studies of phase transitions in the methane hydrate at high pressures, and discuss the inconsistent results by investigating the experimental details. (author abst.)