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Accession number;02A0151814
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| Title;Substituent effect on redox potential of nitrido technetium complexes with Schiff base ligand : Theoretical calculations. |
| Author;
TAKAYAMA T
(Graduate School Of Sci. Tohoku Univ., Japan)
SEKINE T
(Graduate School Of Sci. Tohoku Univ., Japan)
KUDO H
(Graduate School Of Sci. Tohoku Univ., Japan)
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Journal Title;Abstracts of Papers. Symposium on Radiochemistry
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Journal Code:F0139B
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ISSN:1345-2762
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VOL.45th;NO.;PAGE.36(2001)
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| Figure&Table&Reference;FIG.2 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Theoretical calculations were performed for an understanding of the experimental results of the redox potentials between the Tc(V) and Tc(VI) oxidation states of technetium nitrido complexes with salen type Schiff base ligands. The result of calculation indicates that the redox potential of the nitrido technetium complexes with salen type ligands is correlated with the HOMO energy as well as the charge population on the technetium atom. (author abst.) |
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