The crystal structure of rengeite, Sr4ZrTi4(Si2O7)2O8.
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Accession number;02A0408703
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| Title;The crystal structure of rengeite, Sr4ZrTi4(Si2O7)2O8. |
| Author;
MIYAWAKI R
(National Sci. Museum, Tokyo, Jpn)
MATSUBARA S
(National Sci. Museum, Tokyo, Jpn)
MIYAJIMA H
(Fossa Magna Museum, Niigata, Jpn)
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Journal Title;J Mineral Petrol Sci
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Journal Code:G0150B
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ISSN:1345-6296
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VOL.97;NO.1;PAGE.7-12(2002)
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| Figure&Table&Reference;FIG.1, TBL.3, REF.14 |
| Pub. Country;Japan |
| Language;English |
| Abstract;The crystal structure of rengeite was analyzed with a single crystal of the type specimen; (Sr3.62Ca0.08Ce0.03Nd0.02Ba0.01Pr0.01).SIGMA.3.76(Ti4.09Zr0.84Al0.04Fe0.02Nb0.02).SIGMA.5.01Si4.11O22, a=13.9830(10), b=5.6722(9), c=11.9960(10).ANGS., .BETA.=114.215(7).DEG., V=867.74(17).ANGS.3, Z=2. A refinement with space group P21/a showed strong correlations between the parameters of oxygen atoms related by pseudo-mirror planes, and gave non-positive mean square displacement parameters for the oxygen atoms. A refinement with space group P21/a and isotropic displacement parameters for oxygen atoms was converged to R1[FrO>4.SIGMA.(FrO)]=0.0523. On the other hand, a refinement with space group C2/m and anisotropic displacement parameters, in which several very weak observed reflections were ignored, was successfully converged to R1=0.0485. No significant differences in atomic parameter could be observed between the refinements with C2/m and P21/a, except for the x of O(1) site. Although the true space group of rengeite is P21/a, the space group can be regarded as pseudo-C2/m. Rengeite is isostructural with perrierite-(Ce). Zirconium in rengeite occupies preferentially one of three octahedral sites, and does not share the site with Ti. Therefore, the formula of rengeite is not Sr4(Ti,Zr)5(Si2O7)2O8, but Sr4ZrTi4(Si2O7)2O8. A re-indexing of the XRD data of strontio-chevkinite with reference to those of rengeite suggested that strontio-chevkinite might be an Fe-rich variety of rengeite. (author abst.) |
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