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Accession number;02A0418852
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| Title;Reaction of Bromo-Subsutituted Silacyclopropene with Triethylsilyl Cation. |
| Author;
MURAKAMI YASUYUKI
(Univ. of Tsukuba)
FUKAYA NORIHISA
(Univ. of Tsukuba)
KABE YOSHIO
(Univ. of Tsukuba)
SEKIGUCHI AKIRA
(Univ. of Tsukuba)
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Journal Title;Nippon Kagakkai Koen Yokoshu
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Journal Code:S0493A
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ISSN:0285-7626
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VOL.81st;NO.1;PAGE.1(2002)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The reaction of halogen-substituted silacyclopropene with triethylsilyl cation has been investigated. The expected halogen abstraction by triethylsilyl cation did not take place. Alternatively, the silacyclopropene underwent a methyl group elimination followed by a ringexpansion to give the unusual halogen-bridged silylcation. The structure, formation mechanism and reactivity of this cation will also be discussed. (author abst.) |
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