Synthesis, Structure, and Reaction of Optically Active Silyl- and Germyl-lithium.
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Accession number;02A0418856
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| Title;Synthesis, Structure, and Reaction of Optically Active Silyl- and Germyl-lithium. |
| Author;
USHIDA YUHEI
(Gakushuin Univ., Fac. of Sci.)
MAEHARA MASAYUKI
(Gakushuin Univ., Fac. of Sci.)
NANJO MASATO
(Gakushuin Univ., Fac. of Sci.)
MOCHIDA KUNIO
(Gakushuin Univ., Fac. of Sci.)
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Journal Title;Nippon Kagakkai Koen Yokoshu
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Journal Code:S0493A
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ISSN:0285-7626
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VOL.81st;NO.1;PAGE.2(2002)
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| Figure&Table&Reference;FIG.1 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Optically Active Group 14-Element Centered Anions, (R)-t-butylmethylphenylsilyllithium(1) and (R)-t-butylmethylphenylgermyllithium(2), were prepared by use of (-)sparteine. 1 and 2 were characterized by 1H,7Li, and 13C NMR and X-ray diffraction. Optical purity of 1 and 2 was evaluated as corresponding silane and germane by HPLC on optically active stationary phase after hydrolysis. (author abst.) |
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