Mechanism for the Reactions of tris(trimethysilyl)silyl, germyl, and-atannyl anion with Alkyl Halides.
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Accession number;02A0418857
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| Title;Mechanism for the Reactions of tris(trimethysilyl)silyl, germyl, and-atannyl anion with Alkyl Halides. |
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Journal Title;Nippon Kagakkai Koen Yokoshu
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Journal Code:S0493A
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ISSN:0285-7626
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VOL.81st;NO.1;PAGE.3(2002)
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| Figure&Table&Reference;FIG.1 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Silyl, germyl, and stannyl anions with trimethylsilyl group as substituent are stable to be isolated, so they can be treated with several reactants under same conditions. We studied the reactions of these anions with several alkyl halides by stopped-flow technique, and investigated the differences of the reaction mechanism in the difference of the centered atom for anions. (author abst.) |
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