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Accession number;02A0418864
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| Title;Synthesis and Reactions of the First Stannole Dianion. |
| Author;
HAGA RYUTA
(Saitama Univ., Fac. of Sci.)
SAITO MASAICHI
(Saitama Univ., Fac. of Sci.)
YOSHIOKA MICHIKAZU
(Saitama Univ., Fac. of Sci.)
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Journal Title;Nippon Kagakkai Koen Yokoshu
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Journal Code:S0493A
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ISSN:0285-7626
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VOL.81st;NO.1;PAGE.4(2002)
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| Figure&Table&Reference;REF.1 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The first synthesis and reactions of stannole dianion 3 are reported. Reaction of the novel bi(1,1-stannole) 1 with lithium gave the first stannole monoanion 2. Further reduction of the stannole monoanion 2 gave the first stannole dianion 3. The 119Sn chemical shift of the stannole dianion 3 was downfield-shifted compared to that of the bi(1,1-stannole)1, suggesting the delocalization of the negative charge into the stannole ring. (author abst.) |
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