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Accession number;02A0421398
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| Title;Studies on Reaction Mechanism of Molecular Solid Based on Time-Resolved X-Ray Analysis of Crystalline-State Reaction. |
| Author;
OHASHI YUJI
(Tokyo Inst. of Technology, Graduate School)
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Journal Title;Nippon Kagakkai Koen Yokoshu
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Journal Code:S0493A
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ISSN:0285-7626
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VOL.81st;NO.1;PAGE.A.1(2002)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;It has been found that the reaction proceeds in a crystal without degradation of the single crystal form and such a reaction was named as crystalline-state reaction. The reaction mechanism can be easily clarified by analyzing the intermediate structures with X-ray technique in the process of the reaction. The mechanisms of many crystalline-state reactions have been analyzed by X-rays. For the reactions which is too fast to observe the intermediate structures by X-rays with the conventional four-circle diffractometer, new diffractometers have been designed and made. Many unstable structures including the excited ones have been successfully analyzed with the new diffractometers. (author abst.) |
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