Superweak fluoroanions. Synthesis, coordination to metal ions, and practical applications.
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Accession number;02A0620399
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| Title;Superweak fluoroanions. Synthesis, coordination to metal ions, and practical applications. |
| Author;
STRAUSS S H
(Colorado State Univ., Co, Usa)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.6-7(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;Recent work with metal-complex salts of fluorocarboranes, fluoroboranes, fluoro-aminoboranes, and four-coordinate borates and aluminates with polyfluoroalkoxide and polyfluorodialkoxide substituents will be presented, including the synthesis of several new (unpublished) fluoroanions. The applications will include the isolation of novel nonclassical metal-carbonyl cations, catalysis, and the study of new electrolytes for lithium batteries. The lecture will also include a discussion of some of the fundamental principles related to the coordination of weakly basic C-F and B-F bonds to metal ions. (author abst.) |
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