Chemistry with Superweak Anions: Gas Phase Species in the Solid State.
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Accession number;02A0620400
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| Title;Chemistry with Superweak Anions: Gas Phase Species in the Solid State. |
| Author;
GONSIOR M
(Univ. Karlsruhe, Karlstuhe, Deu)
KROSSING I
(Univ. Karlsruhe, Karlstuhe, Deu)
MUELLER L
(Univ. Karlsruhe, Karlstuhe, Deu)
RAABE I
(Univ. Karlsruhe, Karlstuhe, Deu)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.8(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;We report on the synthesis and characterization of a series of very weakly coordinating anions of perfluoroalkyl aluminate anions. These anions produce "pseudo gas phase conditions" in the solid state that allow to isolate and characterize gas phase species in condensed phases: the reactions of Ag[Al(OR)4] with weak Lewis bases L such as S8, P4, etc. led to Ag(L)+ and Ag(L)2+ complexes that are initially observed in the gas phase by MS but now are fully characterized in condensed phases. (author abst.) |
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